B~T
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@DB - A good moveset for a Raichu would be:
Adamant -- Item: Leftovers
- Volt Tackle
- Substitute
- Focus Punch
- Grass Knot/Encore
Use Substitute and then use Focus Punch. The opposing Pokemon will hit your Substitute if it lives and lets you use Focus Punch successively. Grass Knot is there as to hit Water/Ground types that'll wall you. If you used your Grass Knot already, or you don't want to waste a one-copy only TM like me, go with Encore instead to make things a bit easier. Volt Tackle insists that you want a Physical Raichu, so there you go. Leftovers recovers you from the HP wasted from those Substitutes and Volt Tackle recoils.
A Special based Raichu:
Modest/Timid -- Item: Choice Specs
- Nasty Plot
- Thunderbolt
- Focus Blast
- Grass Knot/Hidden Power Ice
Nasty Plot to boost your Special Attack power, and sweep. Grass Knot for the same above purpose, or Hidden Power Ice for defensive Grass or Ground types and to do some decent damage to a walling Altaria.
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